Cabinet ministers agreed "on the need to take action" in Syria to "deter the further use of chemical weapons", Downing Street has said. "It is not about regime change", May said in a statement minutes after U.S. President Donald Trump announced the strikes.
French President Emmanuel Macron claimed that France had "proof" the Assad regime used chemical weapons in Douma at the weekend, and would support any USA action.
Questions were also raised to May at her press conference at 10 Downing Street, which came just hours after the launch of the joint military attack, as to why her government did not first ask for the approval from the British Parliament and the authorisation by the UN Security Council.
Worldwide investigators are due to begin work in Syria on Saturday to determine if in fact banned weapons were used.
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"Cabinet agreed that the Assad regime has a track record of the use of chemical weapons and it is highly likely that the regime is responsible for Saturday's attack", said the statement.
The British government has signaled it is ready to back United States military action against Syria, saying it is "highly likely" the Assad regime used chemical weapons on its own people and that such action could not go unchallenged. Moscow has denied any involvement.
Sturgeon said the suspected use of chemical weapons was "sickening", but warned that the latest action risked "dangerous escalation".
May's office said she had spoken to the Crown Prince of Saudi Arabia, Mohammed bin Salman, Turkish President Tayyip Erdogan, German Chancellor Angela Merkel and the prime ministers of Italy, Australia and Canada about the strikes.
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"The Prime Minister said it was a further example of the erosion of worldwide law in relation to the use of chemical weapons, which was deeply concerning to us all".
President Emmanuel Macron told French media he had "proof" chlorine gas was used in Douma.
"Bombs won't save lives or bring about peace", he said.
"Britain should be playing a leadership role to bring about a ceasefire in the conflict, not taking instructions from Washington and putting British military personnel in harm's way", Corbyn said.
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