"Three people have moderate injuries and another three people have serious injuries", Meerbusch fire department said in a statement.
Almost 50 commuters were injured after a passenger train carrying 155 people hit a freight train northwest of the city of Düsseldorf Tuesday evening.
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A photo tweeted by the Meerbusch fire service showed the passenger train partially derailed but still upright. Meerbusch is in North Rhine-Westphalia, Germany's most populous state.
The collision took place near the Meerbusch-Osterath railway station, where the passenger train rammed from behind into the freight train, which parked on the same track.
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The National Express driver was freed from his mangled cab by firefighters, the federal police said.
The regional passenger train RE7 operated on the track from Rheine to Krefeld.
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A German government spokesman said Chancellor Angela Merkel had been briefed on the situation.